An Electromagnetic Model for Evaluating Temporal Water Content Distribution and Movement in Cyclically Soaked Mortar

Evaluation of water distribution and its temporal movement in cement-based materials is important for assessing cement hydration, curing, and long-term performance. From a practical standpoint, it is also important to obtain this information nondestructively. Near-field microwave nondestructive evaluation methods have proven effective for evaluation of cement-based materials for their various mixture properties, including the detection of salt added to the mixing water and chloride ions entering these materials through exposure to salt water solutions. Electromagnetic modeling of the interaction of microwave signals with moist cement-based materials can provide the necessary insight to evaluate water content distribution and movement in these materials. To this end, the temporal microwave reflection properties of a mortar cube, subjected to cycles of wetting and drying, were measured at 3 and 10 GHz using open-ended rectangular waveguides for several cycles, each lasting about 35 days. A semiempirical electromagnetic model, based on modeling the cube as a layered structure with each layer having a different dielectric constant, was then developed to simulate the measured reflection properties. The simulated and measured results were obtained for both frequencies and, for all cycles, were in good agreement. The most important outcome of the model is the temporal behavior of water content distribution and, hence, its movement in the mortar cube. This paper presents a brief description of the measurement approach and a detailed description of the model. A detailed discussion of the results and its sensitivity to various parameters is also provided

Evaluation of Microwave Reflection Properties of Cyclically Soaked Mortar Based on a Semiempirical Electromagnetic Model

Detection of chloride ingress and evaluation of its distribution and temporal movement in reinforced concrete structures is an important practical issue. Steel reinforcing bars embedded in good quality concrete are normally protected from corrosion. However, the presence of a sufficient concentration of free chloride ions in the region of the reinforcing steel can initiate the process of corrosion. Therefore, it is important to be able to detect ingress of chloride ions and their distribution in cement-based materials. Moreover, it is important to obtain this information nondestructively. In recent years, near-field microwave nondestructive evaluation methods, using open-ended rectangular waveguide probes, have proven effective for evaluating many important properties of cement-based materials, including the detection of salt, added to the mixing water and when entering these materials through exposure to salt solution. Additionally, successful electromagnetic modeling of the interaction of microwave signals with moist cement-based materials has provided the necessary insight for evaluating the distribution and movement of moisture within these materials, leading to the current study involving ingress of sodium chloride solution. To this end, a mortar cube was subjected to cycles of wetting in a sodium chloride bath with a salinity of 2.8%, followed by episodes of drying. Subsequently, the microwave reflection properties of the cube were measured at 3 and 10 GHz using open-ended rectangular waveguides for several cycles, each lasting about 35 days. A semiempirical electromagnetic model, representing the cube as a stratified structure with a nonuniform dielectric property profile, was then developed to simulate the measured reflection properties. The simulated and the measured results at both frequencies and for all cycles were in good agreement. Subsequently, the effect of ingress of salt solution in terms of the temporal distribution of moisture along with the dissolved salt (i.e., pore solution) within the cube for every cycle was also estimated. This paper presents a brief description of the measurement approach and a detailed description of the model and its results

Electromagnetic Modeling of Saltwater Ingress in Mortar at Microwave Frequencies

Corrosion of reinforcing steel is a major cause of damage and deterioration in reinforced concrete structures. Therefore, as the presence of a sufficient concentration of chloride ions can lead to the onset of corrosion in embedded steel, it is of utmost importance to be able to determine the free salt content and its distribution in these materials. Moreover, it is important to obtain this information nondestructively. Previous investigations have shown the capability of near-field microwave nondestructive evaluation methods, using open-ended rectangular waveguide probes, to evaluate many important properties of cement-based materials. In this Investigation, the temporal microwave reflection properties of a mortar cube, subjected to cycles of wetting in a saltwater bath with a salinity of 2.8% and drying were measured at 3 GHz and 10 GHz using open-ended rectangular waveguides for several cycles, each lasting about 35 days. A semi-empirical electromagnetic model was then developed, representing the cube as a stratified structure with a dielectric constant profile to simulate the measured reflection properties. The issue of representing a continuous media as a stratified structure was also explored. The simulated and the measured results at both frequencies, and for all cycles were In good agreement. Subsequently, the volumetric free salt distribution, left In the cube, was also calculated. This paper presents a brief description of the model and its results at 3 GHz for the first cycle

Determination of Dielectric Property Profile in Cement-Based Materials using Microwave Reflection and Transmission Properties

Microwave characterization methods are effective means for evaluating dielectric properties of materials and correlating them to their important physical, chemical and mechanical properties. For characterization purposes most materials are considered homogeneous and the measurement of their dielectric properties is fairly straightforward. However, certain materials may be considered inhomogeneous in such a way that their dielectric properties vary in a preferred direction within the material. To evaluate the dielectric property profile of these materials an electromagnetic model is necessary that can be used along with their measured reflection and transmission properties. This paper presents the development of such a model which is subsequently used to determine the dielectric property profile in mortar samples exposed to cyclical ingress of salt solution

Effect of Exposure Conditions on the Long-Term Dielectric Properties of Mortar Samples Containing ASR Gel

Alkali-silica reaction (ASR) is a chemical reaction between alkalis present in portland cement and amorphous or otherwise disordered siliceous minerals in particular aggregates. Through this reaction, reactive silica binds with hydroxyl and alkali ions and forms a gel, known as ASR gel. Recently, microwave materials characterization techniques have shown great potential for detecting ASR in mortar. However, the comprehensive understanding of variables that affect the extent of ASR in mortar and their interaction with microwave signals, in particular the effect of environmental exposure conditions requires more investigations. Therefore, parameters related to these conditions must be considered when using microwave techniques for ASR detection and evaluation. In this paper, the effect of exposure conditions on ASR gel formation and microwave dielectric properties of mortar samples is investigated. To this end, extended measurements of the complex dielectric constants of three different sets of mortar samples are presented at S-band (2.6-3.95 GHz). The samples were cast with potentially reactive ASR-aggregates and subjected to different environmental conditions. The results show slightly different permittivities for the differently stored samples, potentially indicating different amount of ASR gel. This observation was corroborated through UV fluorescence microscopy, where different amounts of ASR gel were observed in the samples. Moreover, the results indicate that ASR gel evolution may be better tracked through loss factor measurements, while pre-existing-gel may be better detected through permittivity measurements

Microwave Reflection and Dielectric Properties of Mortar Subjected to Compression Force and Cyclically Exposed to Water and Sodium Chloride Solution

Corrosion of the reinforcing steel is a major cause of damage and deterioration in reinforced concrete structures such as concrete bridge decks and columns. Chloride intrusion into concrete can lead to depassivation of the steel and initiation of corrosion. Thus, it is very important to be able to nondestructively detect and evaluate the free chloride content in concrete. Near-field microwave nondestructive testing techniques, using open-ended rectangular waveguide probes, have shown great potential for evaluating various properties of concrete, including the successful detection of sodium chloride added to mortar mixing water. In this study, several mortar samples are cyclically soaked in distilled and salt water while also experiencing compression force. Compression force, simulating in-service loading, causes microcracking, which results in increased microcracking and permeability, promoting chloride ingress. The daily microwave reflection and dielectric properties of these samples were measured at 3 GHz. The results show the capability of these microwave measurements for detecting the increased level of chloride permeation and loading as a function of the increasing number of soaking cycles. The influence of salt ingress is shown to be more prominent in the loss factor, while the effect of loading is more evident in the permittivity of the samples

Maternal peripheral blood level of IL-10 as a marker for inflammatory placental malaria

Background: Placental malaria (PM) is an important cause of maternal and foetal mortality in tropical areas, and severe sequelae and mortality are related to inflammation in the placenta. Diagnosis is difficult because PM is often asymptomatic, peripheral blood smear examination detects parasitemia as few as half of PM cases, and no peripheral markers have been validated for placental inflammation. Methods: In a cohort of Tanzanian parturients, PM was determined by placental blood smears and placental inflammation was assessed by histology and TNF mRNA levels. Maternal peripheral blood levels of several immune mediators previously implicated in PM pathogenesis, as well as ferritin and leptin were measured. The relationship between the levels of these soluble factors to PM and placental inflammation was examined. Results: Peripheral levels of TNF, TNF-RI, TNF-RII, IL-1, IL-10, and ferritin were elevated during PM, whereas levels of IFN-[gamma], IL-4, IL-5 and IL-6 were unchanged and levels of leptin were decreased. In receiver operating characteristic curve analysis, IL-10 had the greatest area under the curve, and would provide a sensitivity of 60% with a false positive rate of 10%. At a cut off level of 15 pg/mL, IL-10 would detect PM with a sensitivity of 79.5% and a specificity of 84.3%. IL-10 levels correlated with placental inflammatory cells and placental TNF mRNA levels in first time mothers. Conclusion: These data suggest that IL-10 may have utility as a biomarker for inflammatory PM in research studies, but that additional biomarkers may be required to improve clinical diagnosis and management of malaria during pregnancy.This work was supported by grants from Bill and Melinda Gates Foundation (grant 29202), NIH (R01 AI52059 and TW05509) and Puget Sound Partners for Global Health to P.E.D

Photometric variability in a warm, strongly magnetic DQ white dwarf, SDSS J103655.39+652252.2

We present the discovery of photometric variability in the DQ white dwarf SDSS J103655.39+652252.2 (SDSS J1036+6522). Time-series photometry reveals a coherent monoperiodic modulation at a period of 1115.64751(67) s with an amplitude of 0.442% +/- 0.024%; no other periodic modulations are observed with amplitudes >~0.13%. The period, amplitude, and phase of this modulation are constant within errors over 16 months. The spectrum of SDSS J1036+6522 shows magnetic splitting of carbon lines, and we use Paschen-Back formalism to develop a grid of model atmospheres for mixed carbon and helium atmospheres. Our models, while reliant on several simplistic assumptions, nevertheless match the major spectral and photometric properties of the star with a self-consistent set of parameters: Teff~15,500 K, log g ~9, log(C/He)=-1.0, and a mean magnetic field strength of 3.0 +/- 0.2 MG. The temperature and abundances strongly suggest that SDSS J1036+6522 is a transition object between the hot, carbon-dominated DQs and the cool, He-dominated DQs. The variability of SDSS J1036+6522 has characteristics similar to those of the variable hot carbon-atmosphere white dwarfs (DQVs), however, its temperature is significantly cooler. The pulse profile of SDSS J1036+6522 is nearly sinusoidal, in contrast with the significantly asymmetric pulse shapes of the known magnetic DQVs. If the variability in SDSS J1036+6522 is due to the same mechanism as other DQVs, then the pulse shape is not a definitive diagnostic on the absence of a strong magnetic field in DQVs. It remains unclear whether the root cause of the variability in SDSS J1036+6522 and the other hot DQVs is the same.Comment: Accepted for publication in ApJ. 12 pages, 9 figure

A Detailed Model Atmosphere Analysis of Cool White Dwarfs in the Sloan Digital Sky Survey

We present optical spectroscopy and near-infrared photometry of 126 cool white dwarfs in the Sloan Digital Sky Survey (SDSS). Our sample includes high proper motion targets selected using the SDSS and USNO-B astrometry and a dozen previously known ultracool white dwarf candidates. Our optical spectroscopic observations demonstrate that a clean selection of large samples of cool white dwarfs in the SDSS (and the SkyMapper, Pan-STARRS, and the Large Synoptic Survey Telescope datasets) is possible using a reduced proper motion diagram and a tangential velocity cut-off (depending on the proper motion accuracy) of 30 km/s. Our near-infrared observations reveal eight new stars with significant absorption. We use the optical and near-infrared photometry to perform a detailed model atmosphere analysis. More than 80% of the stars in our sample are consistent with either pure hydrogen or pure helium atmospheres. However, the eight stars with significant infrared absorption and the majority of the previously known ultracool white dwarf candidates are best explained with mixed hydrogen and helium atmosphere models. The age distribution of our sample is consistent with a Galactic disk age of 8 Gyr. A few ultracool white dwarfs may be as old as 12-13 Gyr, but our models have problems matching the spectral energy distributions of these objects. There are only two halo white dwarf candidates in our sample. However, trigonometric parallax observations are required for accurate mass and age determinations and to confirm their membership in the halo.Comment: ApJ Supplements, in pres

The White Dwarf Luminosity Function from SDSS Imaging Data

A sample of white dwarfs is selected from SDSS DR3 imaging data using their reduced proper motions, based on improved proper motions from SDSS plus USNO-B combined data. Numerous SDSS and followup spectra (Kilic et al. 2005) are used to quantify completeness and contamination of the sample; kinematic models are used to understand and correct for velocity-dependent selection biases. A luminosity function is constructed covering the range 7 < M_bol < 16, and its sensitivity to various assumptions and selection limits is discussed. The white dwarf luminosity function based on 6000 stars is remarkably smooth, and rises nearly monotonically to M_bol = 15.3. It then drops abruptly, although the small number of low-luminosity stars in the sample and their unknown atmospheric composition prevent quantitative conclusions about this decline. Stars are identified that may have high tangential velocities, and a preliminary luminosity function is constructed for them.Comment: Accepted for AJ (Jan 2006). 35 pages (includes 10 figures